Scottyk wrote:Remember that the fill % makes no difference to the vapour pressure, it remains the same until all the liquid has changed to gas and then.... well then it's empty.
If a gauge is fitted then the vapour pressure for a given temp will remain constant as along as there is liquid present.
The fill % will only matter in the sense that there is a greater thermal mass in a full canister vs a half empty one and so the point at which gas stops flowing will happen quicker in the half empty one
It certainly does matter if the fuel is a mixture, which most of the bushwalking canisters are. Usually it's propane and either butane or isobutane or both, as well as small amounts of various other unspecified components. As you use a canister these fuels, being of different volatilities, are expelled at different rates. There's an article about this at backpackinglight.com that I believe Roger Caffin wrote or co-wrote. I'm not a BPL member so I have never read it but I'm fairly certain they make this point. Roger and I had a lively email discussion about this in 2005.
Here's an example of measurements I did in my kitchen about eight years ago. Steps: (1) weigh the canister; (2) immerse it in a water bath at 60°F; (3) wait for it to equilbrate; (4) measure the pressure with an attached gauge; (5) vent a quantity of fuel (burned remotely). Lather, rinse, repeat.